(Na0.52K0.44Li0.04)0.97La0.01Ta0.20Nb0.80O3 (KNLTN-La0.01) lead-free subtransparent ceramics was prepared by a conventional sintering technique. The structure and the optical properties of the ceramics were investigated. The room temperature crystallographic indexing revealed the ABO3 perovskite type, tetragonal phase and P4mm point group in the ceramics. The surface and fractured surface SEM micrographs showed a dense microstructure with few micropores in KNLTN-La0.01 ceramics, which was obviously better than for the pure KNLTN ceramics. The refractive indexes of the films were investigated by an ellipsometer and the results show that the KNLTN-La0.01 subtransparent ceramics reveals significant wavelength dependent dispersion. The refractive index ranges from 2.14 to 2.06 with the wavelength increase from 380 nm to 900 nm. The dispersive behavior was analyzed by three parameters of Cauchy dispersion model and the values of the parameters A, B and C are 2.0610 0.0005, 0.0054 0.0003 and 0.00069 0.00004, respectively.